Yes, for solution of Al3+ is acidic. They causes the hydrolysis
of water molecules.
Al(H2O)6 3+ + H2O --> Al(H2O)5(OH) 2+ + H3O +
One of the water ligand, the electrons are attracted towards the
Al3+, as a result, one of the O-H bond is weaken and broke off. The
H+ is transferred to H2O to form H3O+. This account for the
acidity.
The ka of Al(H2O)6 is around 7.9 x 10^-6