15cm3 of a gaseous hydrocarbon, W, was burnt with 95 cm3 of
oxygen. After cooling to r.t.p, the residual gaseuous products
occupied a volume of 80 cm3. On adding aq. NaOH, the volume
decreased to 50cm3.
Vol of O2 in excess = 50cm3
Vol of O2 used = 95 - 50 = 45cm3
Vol of CO2 produced = 80 - 50 = 30cm3
Since 15cm3 of CxHy produced 30cm3 of CO2, x = 2
Since 15cm3 of CxHy used 45cm3 of O2, 15 (x + y/4) = 45
2 + y/4 = 45 / 15
y/4 = 1
y = 4
Hence hydrocarbon is ethane, C2H4.