Kimberlite
Kimberlite is an ultrapotassic, ultramafic,
igneous rock composed of olivine, phlogopite, pyroxene and garnet,
with a variety of chemically anomalous trace minerals.

Hewn kimberlite
core sample from the James Bay Lowlands region of Northern Ontario,
Canada. Green olivine grains and purplish red garnet are visible.
The sample is 13 cm (5 inches) long.
Morphology and volcanology
Kimberlites are found as dikes and volcanic pipes which underlie
and are the source for rare and relatively small explosive
volcanoes (maars). Kimberlites in the Guyana Shield, in Venezuela
and French Guyana, form thin, tabular dipping sills.
Kimberlite pipes are the result of explosive diatreme volcanism
from very deep mantle derived sources. These volcanic explosions
produce vertical columns of rock that rise from deep magma
reservoirs. The morphology of kimberlite pipes are varied but
generally include a sheeted dyke complex of tabular, vertically
dipping feeder dykes in the root of the pipe which extend down to
the mantle. Within 1.5-2 km of the surface the highly pressured
magma explodes upwards and expands to form a conical to cylindrical
diatreme, which erupts to surface. The surface expression is rarely
preserved but is usually similar to a maar volcano.
Petrology
Kimberlites are divided into Group I (basaltic) and Group II
(micaceous) kimberlites. This division is made along mineralogical
grounds.
The general consensus reached on kimberlites is that they are
formed deep within the mantle, at between 150 and 450 kilometres
depth, from anomalously enriched exotic mantle compositions, and
are erupted rapidly and violently, often with considerable CO2 and
volatile components. It is this depth of melting and generation
which makes kimberlites prone to hosting diamond xenocrysts.
The mineralogy of Group I kimberlites is considered to represent
the products of melting of lherzolite and harzburgite, eclogite and
peridotite under lower mantle conditions. The mineralogy of Group
II kimberlites may represent a similar melting environment to that
of Group I kimberlites, the difference in mineralogy being caused
by the preponderance of water versus Ócarbon dioxide.
Group I
kimberlites
Group I kimberlites are of CO2-rich ultramafic potassic igneous
rocks dominated by a primary mineral assemblage of forsteritic
olivine, magnesian ilmenite, chromian pyrope, almandine-pyrope,
chromian diopside (in some cases subcalcic), phlogopite, enstatite
and of Ti-poor chromite. Group I kimberlites exhibit a distinctive
inequigranular texture cause by macrocrystic (0.5-10 mm) to
megacrystic (10-200 mm) phenocrysts of olivine, pyrope, chromian
diopside, magnesian ilmenite and phlogopite in a fine to medium
grained groundmass.
The groundmass mineralogy, which more closely resembles a true
composition of the igneous rock, contains forsteritic olivine,
pyrope garnet, Cr-diopside, magnesian ilmenite and spinel.
Group II
kimberlites
Group-II kimberlites (or orangeites) are ultrapotassic, peralkaline
rocks rich in volatiles (dominantly H2O). The distinctive
characteristic of orangeites is phlogopite macrocrysts and
microphenocrysts, together with groundmass micas that vary in
composition from phlogopite to "tetraferriphlogopite" (anomalously
Fe-rich phlogopite). Resorbed olivine macrocrysts and euhedral
primary crystals of groundmass olivine are common but not essential
constituents.
Characteristic primary phases in the groundmass include: zoned
pyroxenes (cores of diopside rimmed by Ti-aegirine); spinel-group
minerals (magnesian chromite to titaniferous magnetite); Sr- and
REE-rich perovskite; Sr-rich apatite; REE-rich phosphates
(monazite, daqingshanite); potassian barian hollandite group
minerals; Nb-bearing rutile and Mn-bearing ilmenite.
Kimberlitic indicator
minerals
Kimberlites are peculiar igneous rocks because they contain a
variety of mineral species with peculiar chemical compositions.
These minerals such as potassic richterite, chromian diopside (a
pyroxene), chromium spinels, magnesian ilmenite and high-aluminium
garnets are generally absent from most other igneous rocks, making
them particularly useful as indicators for kimberlites.
These indicator minerals are generally sought in stream sediments
in modern alluvial material. Their presence, when found, may be
indicative of the presence of a kimberlite within the erosional
watershed which has produced the alluvium.
Economic importance
Kimberlites are the most important source of primary diamonds. Many
kimberlite pipes also produce rich alluvial or eluvial diamond
placer deposits.
The deposits occurring at Kimberley, South Africa were the first
recognized and the source of the name. The Kimberley diamonds were
originally found in weathered kimberlite which was colored yellow
by limonite, and so was called yellow ground. Deeper workings
encountered less altered rock, serpentinized kimberlite, which
miners call blue ground.
Issue #395